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Wood stain is not flammable after it dries. The solvent in wood stain is what causes the liquid form to be highly flammable, but the stain drying process involves the solvents dissolving, which leaves behind a non-flammable product on your wood project. Wood stain is, however, flammable before you apply it, so you should always store partially full cans and used wood stain rags away from sources of heat and open flames.

If possible, it is beneficial to paint both sides of your fence to protect the fence more completely from the elements. Painting both sides of your fence will create a more consistent appearance as well. However, the time and cost involved in painting both sides of the fence may cause people to paint only the side they see.

Stains penetrate wood best when it's cool and dry, so you want to avoid moisture. If the wood is wet upon application, or if it rains before the stain dries, the water will soak into the wood and displace the staining solution. This leads to a flaky and blotchy look, which is the opposite of a sumptuous even coat. Once the stain has fully cured, after about 3 days, rain shouldn’t cause you any problems.

You should repaint your fence every 1 to 3 years, depending on the appearance of wear and tear. Weather and usage will factor into how often you should paint another coat on your fence. If you need to replace a few fence boards or posts, you may want to consider repainting the fence to help protect the rest of the fence as well as the new pieces against damage and deterioration from being exposed to the elements.