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Some snake repellents are risky to use around people and pets because they use the active ingredient in mothballs, naphthalene. The United States Environmental Protection Agency (EPA) has classified naphthalene as a carcinogen that can cause damage to the liver, neurological issues, and cataracts. 

The Colorado State University Extension suggests there’s not enough conclusive evidence of the effectiveness of snake repellents to recommend their use.

Deer rely on scent to tell them what’s safe and unsafe, so effective deer repellents have to be pungent. Make your own natural repellent by combining a beaten egg, one tablespoon of cooking oil, one tablespoon of dish soap, and a half cup of milk. Pour it into a spray bottle and spray around your garden, avoiding anything you will want to eat later. This stinky repellent will ward off any deer that want to make your produce their next meal. But keep in mind that if your windows are nearby, the scent may waft over.

This varies based on the circumstance. Chemical-based pest control baits and poisons are usually the most potent, but they are unsafe to use around children and pets, so they won’t be a fit for every household.

Safer alternatives, such as boric acid and food-grade diatomaceous earth, can work as well, though they should still stay out of reach. Aside from that, the best thing any DIY-er can do is make their place uninviting by sealing off entry points, eliminating clutter, and maintaining a clean home.

Tree sap is not usually dangerous to humans or pets. But some trees do produce dangerous sap. Notably, ash, birch, cedar and similar saps can irritate the skin but aren’t dangerous. Sap from trees like the Brazilwood, Mahogany, Milky Mangrove or well-named Poison Walnut can be corrosive, cause nausea, or trigger those with asthma. But for most backyard trees, protective equipment like a sturdy pair of gloves should be fine.