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No. Removing the cause of concern will only lead to deeper concern. You cannot use any fire-powered appliance like a fireplace or furnace without an escape route for the smoke and fumes. If you remove the flue intending to repair or replace it, you should only use the fireplace, wood stove, or furnace once the flue is in working order. If you cannot replace the flue you have removed, call a chimney repair professional immediately.

Baking soda is an effective fire reduction method. However, flour and baking powder are very dangerous around flames. Flour is flammable and it can also conduct electricity. The combination can cause serious injury from electrical shock and worsen the situation by adding fuel to the fire. Baking powder is also not an option as it's also highly flammable. 

The primary disadvantage of a ventless fireplace is that it doesn’t have an exterior venting system. This means that the byproducts from combustion are emitted into your home, which raises some safety concerns. In addition, ventless gas fireplaces produce moisture as they burn—and if there’s no ventilation, you could end up with a mold problem.

Regular inspections, battery replacements, and testing alarms help maintain reliability.