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Yes, you can waterproof any wood that has not already been treated. A good way to test this is to splash some water on it. If the water starts to bead up, the wood is treated and most likely doesn’t need another coating.

Adding a second coat of stain to wood can even out the color to some extent, but it won't drastically alter the hue if the initial application is too light or too dark. It's more effective at enhancing the richness of the color rather than significantly changing it. Ensure the first coat is dry before applying the second.

Whether to brush or roll stain on wood depends on the project and your preference. Brushing is ideal for smaller, intricate areas and offers more control over the application, ensuring thorough coverage and penetration into the wood's grain. 

Conversely, rolling is efficient for more extensive, flat surfaces and can save time. However, it is not always the best fit for textured or uneven wood. Some projects may benefit from combining both methods, using a brush for detail work and a roller for broader areas. Ultimately, the choice between brushing and rolling depends on the specific requirements of your staining project.

Liquid rubber is great for waterproofing, but it can damage your deck if it’s not applied correctly. First, it can trap moisture in the wood if the deck isn’t completely dry before application.  Second, applying it too thickly can create a heavy, rubbery surface layer that peels and cracks under fluctuating temperatures. For the best results, ensure the wood is completely dry before application, and apply the liquid rubber in thin, even coats. A quick inspection every now and then will help you catch any issues early, keeping your deck protected and looking its best.