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Grout and caulk are commonly used together, especially in bathrooms. Grout goes between the tiles and keeps them sturdy and in place on the walls or floor. Caulk goes in corners or where two different materials meet (like where the bathtub meets the tile) to create a waterproof seal. However, they are not interchangeable—you shouldn't use caulk to adhere tile and shouldn’t use mortar if you need a waterproof seal.

Grouting hearth tiles is one of the most important steps. It seals the tiles so heat doesn’t transfer under the tiles so easily, which can be dangerous. For this reason, heat-resistant grout is a must. Grout also prevents dust, dirt, and any other material from gathering between your tiles. If this happens and those buildups are flammable, a fire could start between the tiles. 

Yes, but you should only put tile directly on drywall in smaller areas that don’t experience excess moisture. For example, a small kitchen tile backsplash could work, but installing tile directly on the drywall in a bathroom or other chronically damp area is not a good idea. Either way, a cement backer board is a far more reliable solution, as drywall is susceptible to moisture and can warp or cause your tiles to crack.

Options include clay, concrete, and slate tiles. Each offers unique durability, aesthetics, and costs.