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Yes, windows being painted shut is a fire hazard. Because windows painted shut may have locks that stick or cannot be opened easily in an emergency, this becomes an immediate fire hazard that should be dealt with.

You should have either an ABC or K-rated fire extinguisher in the kitchen. ABC fire extinguishers put out wood, trash, paper, plastic, and textile fires along with grease, oil, gas, kerosene, and electrical fires. A class K fire extinguisher is specifically rated for use in the kitchen and is designed to extinguish combustible cooking materials, including grease and fat. 

Ensure you have a safe environment for them to work on, and there aren’t items such as logs, build-up of yard materials, missing or damaged shingles, and weak areas on the roof. Communicate any known electrical issues with contractors at the beginning of the project, and consider hiring an electrician to fix those. Finally, if you are attempting the project yourself, do so when there isn’t any rain, and you can safely get your footing on the roof using proper equipment, such as an extension ladder. Don’t attempt this alone, and have a helper nearby to assist.

You can fireproof an existing door to some extent, but it's better to remove the old door and replace it with a fire-rated model. Anything dealing with extreme heat needs rigorous testing and a door you DIY fireproof will not undergo the same safety measures as a premade one. Consider a door with a rating of at least 30 minutes or more in residential areas.