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Stains penetrate wood best when it's cool and dry, so you want to avoid moisture. If the wood is wet upon application, or if it rains before the stain dries, the water will soak into the wood and displace the staining solution. This leads to a flaky and blotchy look, which is the opposite of a sumptuous even coat. Once the stain has fully cured, after about 3 days, rain shouldn’t cause you any problems.

Yes, you can paint galvanized chain link, but the process is a bit more difficult as it requires additional prep work. Before applying the primer and paint, you must remove the original coating from the metal, which can be time-consuming. If the original coating is not removed, the primer and paint will not bond properly and cause peeling over time.

While power washing isn't a requirement before you stain a fence, it can make the job much easier and faster while reducing manual labor requirements. The stain will not work if the wood is full of dirt and dust, so power washing, sometimes called pressure washing, is a fast and effective way to prepare the wood for staining. Remember that you need to stain or repaint relatively soon after the wood has dried so that there isn’t time for dust and dirt to build up again. 

While the answer varies based on weather, 10 a.m. is a good time to start painting. The dew will have dried, meaning there’s no moisture on the house, and the temperature will likely be moderate and the sunlight less direct. Starting mid-morning should also give you enough daylight and pleasant weather to work on the job for several hours.