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You can let a fire burn out in a fireplace as long as you or someone else will stick around to monitor it until it goes completely out. This may take several hours. To prepare, stop adding fuel to the fire well before you’re ready to call it a night. If you’re using the fireplace for warmth, you’ll want to cover up in some blankets as the flame dies down.

Baking soda is an effective fire reduction method. However, flour and baking powder are very dangerous around flames. Flour is flammable and it can also conduct electricity. The combination can cause serious injury from electrical shock and worsen the situation by adding fuel to the fire. Baking powder is also not an option as it's also highly flammable. 

Regular HVAC filter changes, deep cleaning, and air quality monitoring help maintain a healthy environment.

In some cases, you can use a fireplace once the insert has been removed. However, before burning a fire, you must have a professional inspect it and the chimney to make sure they're functioning properly and no damage has occurred from removing the insert. That’s because using a fireplace without an insert could create fire hazards due to issues with airflow and heat dispersion, depending on the fireplace design and material. A professional can advise on whether you should make certain repairs or modifications before using your fireplace as an open hearth.