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Baking soda is an effective fire reduction method. However, flour and baking powder are very dangerous around flames. Flour is flammable and it can also conduct electricity. The combination can cause serious injury from electrical shock and worsen the situation by adding fuel to the fire. Baking powder is also not an option as it's also highly flammable. 

No, you should never leave a fireplace burning overnight or unattended during the day. While fireplaces are made to contain fires, fires can and do spread from fireplaces, so it’s crucial that you’re there to monitor them and put them out if needed. If you’re worried about putting out a fire before bed, stop feeding it fuel long before bedtime and actively put out the fire using your poker, a shovel, and some baking soda.

There aren’t many problems with fire doors except that they slow down or cut off ventilation at the higher rating levels. For this reason, work with a professional to ensure you have adequate ventilation throughout your house or workspace. The sealing around a fire door is meant to allow for a specific amount of ventilation and will need regular inspections to ensure adequate airflow.

Yes, you can close off a fireplace both temporarily and permanently with extremely wide price ranges. Temporary solutions involve fireplace plugs that can be inflated to block air and deflated to open the fireplace, covers, and boards. Permanent methods of shutting off fireplaces usually involve bricking up the fireplace or covering it with drywall. No matter the method, it’s probably best to hire a professional.