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Yes, you should seal and cap an unused chimney to protect it from damage. Sealing the structure helps prevent moisture damage, which can lead to issues like cracks, spalling, efflorescence, and damaged mortar joints. Capping the chimney is also crucial to prevent blockages, damage from invasive critters, and downdrafts, while still allowing for proper air ventilation to manage moisture. For the best results, consult a chimney professional to select the right type of chimney or flue cap for your home. It's also wise to continue with annual chimney inspections to maintain the structure's integrity.

Yes, you can close off a fireplace both temporarily and permanently with extremely wide price ranges. Temporary solutions involve fireplace plugs that can be inflated to block air and deflated to open the fireplace, covers, and boards. Permanent methods of shutting off fireplaces usually involve bricking up the fireplace or covering it with drywall. No matter the method, it’s probably best to hire a professional.

Baking soda is an effective fire reduction method. However, flour and baking powder are very dangerous around flames. Flour is flammable and it can also conduct electricity. The combination can cause serious injury from electrical shock and worsen the situation by adding fuel to the fire. Baking powder is also not an option as it's also highly flammable. 

No. Removing the cause of concern will only lead to deeper concern. You cannot use any fire-powered appliance like a fireplace or furnace without an escape route for the smoke and fumes. If you remove the flue intending to repair or replace it, you should only use the fireplace, wood stove, or furnace once the flue is in working order. If you cannot replace the flue you have removed, call a chimney repair professional immediately.