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Yes, usually you will need some kind of vapor barrier on the exterior walls when the framing is attached to concrete and masonry surfaces.

Yes, basement insulation needs a vapor barrier due to its susceptibility to moisture seeping in from the outside of the house. You should install a moisture barrier before you install insulation or purchase insulation that comes prebuilt with a moisture barrier to avoid water damage in your insulation and costly mold and water remediation expenses. 

Ductwork should be wrapped in insulation in certain locations. This includes unconditioned interior parts of the home, such as attics, crawl spaces, basement ceilings, and between floors. Duct joints should also be insulated since they're more likely to leak air than other parts of your system. Building codes in some areas also require ductwork to be insulated.

In some areas, insulation companies require a special license, while some states only require them to hold general contractor licenses. Some municipalities may not mandate any license, although you should always ensure a contractor is fully insured. You can use Angi’s license lookup tool to confirm whether or not an insulation contractor you’re considering holds the necessary license for your area. You can also contact the company for information regarding licenses, certifications, and insurance.