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Yes, steam cleaning can be an effective way to clean a couch, but whether it's recommended depends on the upholstery material. It is possible to steam clean some couches, particularly those made of durable fabrics like cotton or polyester. However, not all materials handle heat and moisture well; delicate fabrics such as silk and rayon should only be dry-cleaned to avoid damage.

Before you begin, always double-check your couch manufacturer’s cleaning recommendations. If steam cleaning is appropriate for your couch, opt for a gentle steam cleaner designed for fabric rather than a bulky carpet cleaner, and use the gentlest setting to prevent damage to the fabric and foam padding. Like with carpets, you may need to pretreat and spot-clean tougher stains.

While effective, steam cleaners can be expensive to buy or rent. If you are unsure about the material or the process, it's best to call a professional upholstery cleaning service to avoid causing damage.

Steam and vinegar are excellent cleaners, but it’s best not to put vinegar in your steam cleaner unless explicitly approved by the manufacturer. If you don’t dilute the vinegar properly, it can damage the steam cleaner, and using a non-approved cleaning solution in the machine can void the manufacturer’s warranty.

The fastest way to soak up water in carpet is to use a wet/dry shop vac to draw out as much water as possible. Afterward, apply firm pressure to towels to sop up any remaining moisture, then liberally sprinkle baking soda over the carpet and let it sit for at least an hour before vacuuming it up. You can speed up the process by opening windows, using blower fans to create airflow, and running a dehumidifier. 

The duration of mildew smell in carpets depends on several factors, including the extent of moisture, cleanliness, and ventilation. If promptly addressed, the smell can diminish within a few days to a couple of weeks after thoroughly drying and cleaning the carpet. However, in severe cases or if not properly treated, the smell might persist. Persistent odors could indicate deeper mildew growth, requiring professional cleaning or, in extreme cases, carpet replacement to completely eliminate the smell.