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Stains penetrate wood best when it's cool and dry, so you want to avoid moisture. If the wood is wet upon application, or if it rains before the stain dries, the water will soak into the wood and displace the staining solution. This leads to a flaky and blotchy look, which is the opposite of a sumptuous even coat. Once the stain has fully cured, after about 3 days, rain shouldn’t cause you any problems.

While power washing isn't a requirement before you stain a fence, it can make the job much easier and faster while reducing manual labor requirements. The stain will not work if the wood is full of dirt and dust, so power washing, sometimes called pressure washing, is a fast and effective way to prepare the wood for staining. Remember that you need to stain or repaint relatively soon after the wood has dried so that there isn’t time for dust and dirt to build up again. 

For homes in areas with extreme weather, high heat, or intense sun exposure, high-quality acrylic paint is the best option. Acrylic paint is durable, resistant to both heat and cold, and provides a protective barrier with excellent UV resistance. For best results, look for acrylics that contain natural earth pigments, which are better suited for resisting sun damage. While oil-based paint is also durable, it can be prone to fading in high heat and can become too viscous to apply easily in cold temperatures. Additionally, choosing a neutral or light color like gray, beige, or white can help, as these colors absorb less heat than darker shades.

If it rains after you paint your fence, you may need to apply another coat of paint after the fence thoroughly dries. This will ensure a good seal if the rain weakened any areas of the paint. However, if your paint had enough time to dry thoroughly before it rained, you should have no problem.