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A spark arrestor is not the same as a chimney cap. Both sit on the top of the chimney. However, the cap keeps debris from entering the chimney, and the spark arrestor’s primary function is to prevent burning embers from escaping. Some spark arrestors are integrated into the chimney cap, and others are installed separately.

Chimney caps are necessary both from a building safety standpoint in most municipalities and to keep your home protected from a variety of issues. Chimney caps are not only mandated by building code in most areas, but they also serve to keep squirrels, raccoons, and other pests out of your home, as well as snow and rain. Therefore, they help to avoid property damage, making them a worthwhile investment.

Baking soda is an effective fire reduction method. However, flour and baking powder are very dangerous around flames. Flour is flammable and it can also conduct electricity. The combination can cause serious injury from electrical shock and worsen the situation by adding fuel to the fire. Baking powder is also not an option as it's also highly flammable. 

A hot fire alone will not remove significant creosote buildup and can be dangerous, as it risks causing a chimney fire. While the warmth from a fire can help loosen stuck tar, making treatments like creosote logs more effective, it is not a substitute for proper cleaning. For existing creosote, the safest and most effective method is to have your chimney professionally cleaned by a chimney sweep.