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The best way to prevent weeds is to use polymeric sand, which hardens and blocks weed growth when activated with water. If you're using regular sand, you'll need to refill and compact it more often. Keeping the surface clean and free of debris can also help prevent weed seeds from settling in the joints.

No, it's not really possible to completely prevent weed growth. Weeds are incredibly resilient—all they usually need is a tiny bit of dirt to sprout, so their eventual appearance is pretty much inevitable. However, you can definitely keep them at bay by getting rid of weeds as soon as you notice them. The longer you let them sit and grow roots, the more they'll spread.

Weeds can grow through rubber mulch, but it depends on if you removed all the weeds in your garden beforehand. Weeds already in the soil can grow even when using rubber mulch. However, that doesn’t mean that your garden will be littered with rubber and weeds, but it does mean that the occasional weed might still pop up. Another way you can increase your weed suppression is by using landscape fabric as a second layer. 

All herbicides come with risks, but you can control and mitigate risks by discussing your options with your weed service company before application. Some companies use milder or sustainable herbicides more times per season to control weeds rather than one to two herbicide sprayings annually. You can also ask your professional about pet-friendly and kid-friendly services. In most cases, though, you can wait a few days after the application for the herbicides to soak into the ground, at that point they shouldn’t pose a risk to you or your family.