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Baking soda is an effective fire reduction method. However, flour and baking powder are very dangerous around flames. Flour is flammable and it can also conduct electricity. The combination can cause serious injury from electrical shock and worsen the situation by adding fuel to the fire. Baking powder is also not an option as it's also highly flammable. 

No, you should never leave a fireplace burning overnight or unattended during the day. While fireplaces are made to contain fires, fires can and do spread from fireplaces, so it’s crucial that you’re there to monitor them and put them out if needed. If you’re worried about putting out a fire before bed, stop feeding it fuel long before bedtime and actively put out the fire using your poker, a shovel, and some baking soda.

A spark arrestor is a simple metal mesh device that prevents flammable particles from escaping from a combustion source and causing a fire. You typically find these attached to gas or diesel engines on things like cars, generators, and garden tools (lawnmowers, chainsaws, etc.). Fireplace or wood-burning stove chimneys also have spark arrestors attached to or sitting under the chimney cap to capture burning embers.

The short answer is yes, but the longer answer is more complex. Unless the fireplace is ventless by design, you’ll need some type of exhaust pipe system to safely send fumes and other harmful byproducts out of the house. Even then, ventless fireplaces are not always permitted because they do keep the byproducts inside of your house. Ventless fireplaces are safest when installed in spaces that are themselves well-ventilated, like large rooms with lots of windows.