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White vinegar does not kill ivy on trees because its acetic acid concentration is not high enough to overpower it. Vinegar is an effective herbicide for weeds and other plants, but not for the strength of most ivies, including poison ivy and English ivy. You should use an herbicide to kill ivy, such as one with glyphosate, imazapyr, or triclopyr.

A tree can grow back from its stump, but full regrowth is unlikely (especially for more stubborn conifer trees). Instead, trees are more likely to send up a number of shoots from the dead stump, which will try to develop into primary stems over time. In other words, it will start to look increasingly bushy. The goal of killing and drying out a tree stump is to prevent that from happening, as well as make the stump easier to completely remove.

A general rule is that trees need 10 gallons of water for each inch of the tree’s diameter. For large trees, that can amount to approximately 160 gallons of water or more. Watering big trees to this extent can take quite a bit of time using a hose. For this reason, you may consider installing a soaker hose or sprinkler system to make the job easier.  

Trees naturally want to grow upward, so one may straighten all by itself, though this only comes into play when a tree is leaning just a small amount. For trees growing into an awkward position or those leaning heavily in one direction, the above steps are necessary to ensure the tree gets back on the right path. This also holds true for trees planted in a spot with unstable soil.