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Yes, mineral spirits are flammable and may spontaneously combust at temperatures of 200 degrees F or more. Storing them in well-ventilated spaces and disposing of them the proper way are the best ways to prevent mineral spirits or anything contaminated with them, like towels and rags, from going up in smoke.

Generally, an oil furnace is considered safer than a gas furnace for several reasons. While both types of furnaces can produce carbon monoxide, a leak in an oil furnace is easier to detect due to the smell. Oil furnaces also don't connect to a gas pipeline, which reduces the chance of a fuel leak. Most importantly, heating oil is not combustible, whereas natural gas is highly flammable. This means there is a much lower risk of combustion or explosion with an oil furnace. However, an oil furnace can still pose a fire hazard if it tips over.

The National Fire Protection Association (NFPA) says you can place smoke detectors on either the ceiling or the wall, depending on the setup of your room. Since smoke rises, the ceiling makes sense, but if you go with a wall mounting, the alarm should be installed high up—no less than 12 inches from the ceiling. 

Although you can put a smoke detector on a shelf, the NFPA recommends mounting one on the ceiling or a wall (within 12 inches of the ceiling). If you place your smoke alarm on a shelf, ensure it’s away from drafty, damp, or dusty areas and not near cooking appliances, heat sources, or fluorescent lights.