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Yes, you can and should paint or stain pressure-treated wood, as this helps prevent the surface from cracking. However, it is crucial to wait for the wood to dry out completely from the chemical treatment process before applying a finish. If the wood is still wet, the paint will not adhere properly. The drying time can range from weeks to six months. To test if the wood is ready, drip some water onto a board. If the water is absorbed, the wood is dry enough for painting or staining. If the water beads up on the surface, it needs more time to dry. You can build with the wood while it's still wet, but you must wait for it to dry before painting.

If possible, it is beneficial to paint both sides of your fence to protect the fence more completely from the elements. Painting both sides of your fence will create a more consistent appearance as well. However, the time and cost involved in painting both sides of the fence may cause people to paint only the side they see.

You shouldn't paint a metal fence. Painting doesn't necessarily damage a corrugated metal fence, but these types of fences are meant to flex, and paint can easily chip and break off. Latex paints can address this issue, but those tend not to be very weather-resistant. Certain paints can trap moisture in the corrugation, which can rust the metal and lead to corrosion. And finally, if you paint a copper fence, it won't patina, which is one of the main reasons people buy copper.  

The number of coats you need to apply when whitewashing a surface depends on how opaque you want the final product to be. If you're going for a transparent, barely there look, a single coat or two may suffice. For fuller coverage, you'll want to use multiple coats. Another option is to use a less diluted paint to get a thicker coverage.