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Grout and caulk are commonly used together, especially in bathrooms. Grout goes between the tiles and keeps them sturdy and in place on the walls or floor. Caulk goes in corners or where two different materials meet (like where the bathtub meets the tile) to create a waterproof seal. However, they are not interchangeable—you shouldn't use caulk to adhere tile and shouldn’t use mortar if you need a waterproof seal.

It’s easiest to start from an edge as it gives you a straight line. A problem may arise if your edge doesn’t line up perfectly, in which case it’s best to start from the center. Some think that starting tile from the center adds a focal point in the center of the hearth. 

Grouting hearth tiles is one of the most important steps. It seals the tiles so heat doesn’t transfer under the tiles so easily, which can be dangerous. For this reason, heat-resistant grout is a must. Grout also prevents dust, dirt, and any other material from gathering between your tiles. If this happens and those buildups are flammable, a fire could start between the tiles. 

You can, in theory, tile your fireplace hearth with most tiles. However just because you can, doesn’t mean you should. For example, it’s much better to use unglazed tiles because glazed tiles are more resistant to cracking under extreme heat. Porcelain is more heat-resistant than ceramic, but you can still design the hearth as you like by putting the most heat-resistant tiles directly under the fire and, if it matches your style, add more decorative tiles further from the center of the fire.