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You can use a chainsaw, but it won’t remove the entire stump or root ball and is not a recommended method. It takes quite a bit of physical work to achieve and will likely dull or ruin your chainsaw. Instead, consider using salt, herbicide, light deprivation, boiling water, stump grinding, or burning to kill a tree stump. These methods allow you to kill a stump using minimal machinery and physical exertion.

Generally speaking, you’ll want to avoid flush cuts, which are cuts made as extremely close to the trunk or main branch. These cuts can weaken your tree, lower its natural defense mechanisms, and even cause decay. You’ll also want to avoid tree topping, which is the total removal of the leader and upper main branches of a tree. 

Most pros will advise against either of these methods, which is why hiring a pro is often the best choice when it comes to tree trimming.

Rock salt or Epsom salt can damage and kill tree roots over several weeks and can even assist in removing the tree's stump. However, you need to drill holes or cut into the stump and surface tree roots to inject them properly with the salt. Repeat the process every two weeks until the roots visibly rot away.

The fastest ways to remove a tree stump are by grinding it or burning it.

Stump grinding is often the quickest method, with professionals able to chip away a stump and its roots within a single session. You have the option to hire a professional stump removal service or rent a stump grinder to do it yourself. However, it's important to note that these machines can be large, difficult to transport, and dangerous to operate without prior experience. For safety reasons, hiring a local arborist or landscape specialist is often recommended.

Burning is another fast option. Before you begin, check your local burn laws. The process involves drilling holes into the stump, filling them with vegetable oil, and waiting 24 to 48 hours. Afterward, you can add charcoal bricks to the surface and light the fire, which must be attended at all times.

For a more affordable but much slower alternative, you can use potassium nitrate pellets to accelerate the natural decomposition process. This method typically takes four to six months.