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No, it's not really possible to completely prevent weed growth. Weeds are incredibly resilient—all they usually need is a tiny bit of dirt to sprout, so their eventual appearance is pretty much inevitable. However, you can definitely keep them at bay by getting rid of weeds as soon as you notice them. The longer you let them sit and grow roots, the more they'll spread.

No, definitely not. Pulling weeds by hand is the single most effective way to remove them because you're eliminating the entire plant—roots and all—so it won’t have a chance to grow or spread. Setting time aside a few times per week to pull weeds can keep them at bay. If the number of weeds gets overwhelming, then you can resort to other methods.

Yes, weeds will grow through pea gravel but you can prevent this during the installation process. Install a weed barrier underneath pea gravel and swap it out every three years to keep weeds at bay.

Glyphosate and other non-selective herbicides can kill orchard grass, but they will also kill the surrounding plants. Also, not all areas allow the use of glyphosate due to its environmental impact—which the EPA describes as a "potential risk to terrestrial and aquatic plants and birds, and low toxicity to honeybees." Consider mechanical removal to target the plants specifically.