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No, you do not have to worry about new popcorn ceilings having asbestos. All residential building materials used since the mid-1980s stopped including asbestos, so new popcorn ceilings have no risk of asbestos. You can still create a textured drywall ceiling with a popcorn texture if you like, but new techniques have no risk of adding asbestos. 

Sampling typically takes 1-3 hours, and depending on the provider, lab results are available within 2-7 days.

There are products that still contain asbestos, but they were typically installed decades ago. Common places where you may still find asbestos-containing materials are in siding, wrapped around ductwork, in older appliances (i.e., stove and gravity furnaces), and in floors. Asbestos was primarily used as an insulator, so anywhere in an older home where you lose heat is where you will most likely find asbestos.

If you own a stereo microscope, you should be able to see the fibers. The stereo microscope often can perform magnification up to 50x. But unless you have experience viewing asbestos fibers, you may not know exactly what you are seeing. Some fibers are curly, while others are long and straight. Blue, brown, white, and gray colored fibers are all possible.