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Squirrels hate not having access to secure shelter or food sources. Your best line of defense is to make your property less attractive by removing access to these things. There are chemical squirrel repellents, but these have mixed success. According to Pennsylvania State University, you can apply products containing the bittering agent denatonium saccharide to a squirrel's favorite fence, tree, or roof spots. However, you need to reapply repellents regularly, which aren’t scientifically proven effective.

Spraying for ticks does a good job of eliminating the existing ticks in your yard. Moderate to severe infestations might require several treatment sessions, but most infestations are well controlled with enough treatments, regardless of their severity.

However, wildlife, pets, and people can still carry ticks into a yard, even after treatment, so if you're concerned about ticks in your area, it's a good idea to spray annually for tick prevention.

Luckily, skunks aren’t challenging to get rid of. You can try to remove them slowly by filling their den entryway loosely with newspaper. Many skunks notice their den is in jeopardy and take off on their own. You can also try making a homemade spray of jalapeno pepper, yellow onion, and cayenne pepper—believe it or not, skunks are sensitive to these smells, so if you spray this around the den or in hard-to-reach places around your property, most skunks will take the hint and leave. 

Chemical treatments, bait systems, and physical barriers are common approaches.