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If you spray a DIY vinegar solution that contains high salt, it can disrupt the soil's structure and make it difficult for plants to grow. That's why it's vital to avoid spraying vinegar solution on areas where you are trying to grow plants and flowers. When using a mix of vinegar and soap, some say you can plant a few days after the vinegar dries. 

It’s not legal to intentionally damage a neighbor’s tree. Even if the roots of a tree encroach into your yard, if you damage or kill a tree that belongs to your neighbor, you can be held liable for the damage in most cases. Since herbicides can spread through the tree, causing damage to the whole tree and not just the roots that are on your side of the property line, you shouldn’t poison your neighbor’s tree. The other downside to this method is that if the tree dies, it can fall onto your property and cause more damage, so herbicides are best avoided in this circumstance.

Yes. One of the main benefits of organic mulch is weed prevention. Organic mulch forms a physical barrier that blocks light and stops weeds from germinating. It can reduce your need to weed and improve the physical appearance of your garden.

Vinegar is known to be a contact herbicide, which means it kills the foliage it comes in contact with. Because of the high acetic acid concentration, horticultural vinegar kills weeds and grass more effectively. However, keep in mind that high amounts and multiple applications can affect the soil by lowering the pH levels.