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Most spray paints are oil-based, meaning you will need a solvent to dissolve them, like paint thinner, lacquer thinner, or acetone. While solvents can be useful in removing paint, they are also very flammable and require the use of a respirator. Beyond that, these products may smear paint and cannot be used on all surfaces.

Scrape softened caulk with a putty knife or slice hardened caulk with a utility knife. Hard-to-remove caulk generally requires more time exposed to a softening solution, like a commercial product or rubbing alcohol. A few hours to a day later, the softened caulk will come off with the help of common household tools. In many cases, you can grab needle-nosed pliers for caulk with multiple old layers and pull the material off its base. 

Professionals may use a variety of methods to remove old paint from surfaces, often depending on the size and complexity of the surface. Paint scraping in combination with a chemical paint stripper is the most common method, but experts might also use heat or steam to loosen everything before peeling the paint off. Some might just sand off the old paint if the surface is relatively flat and easily accessible.

You can find chemical and naturally derived paint thinners to remove paint without as much sanding. A heat gun or pressure washer can also remove paint from large areas. However, sanding is often the best way to remove the final bits of paint that remain on the surface.