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A spark arrestor is not the same as a chimney cap. Both sit on the top of the chimney. However, the cap keeps debris from entering the chimney, and the spark arrestor’s primary function is to prevent burning embers from escaping. Some spark arrestors are integrated into the chimney cap, and others are installed separately.

Yes, dead palm tree fronds are a fire hazard. The leaves become highly combustible because the dead fronds don’t fall off the tree themselves, especially in hot, sunny climates. In fact, many wildfires start from dead palm fronds. Palm trees can also easily catch fire from lighting, electrical power lines, and fireworks. So, cutting off dead palm fronds before they become a fire hazard is important.

Baking soda is an effective fire reduction method. However, flour and baking powder are very dangerous around flames. Flour is flammable and it can also conduct electricity. The combination can cause serious injury from electrical shock and worsen the situation by adding fuel to the fire. Baking powder is also not an option as it's also highly flammable. 

You can fireproof an existing door to some extent, but it's better to remove the old door and replace it with a fire-rated model. Anything dealing with extreme heat needs rigorous testing and a door you DIY fireproof will not undergo the same safety measures as a premade one. Consider a door with a rating of at least 30 minutes or more in residential areas.