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You can let a fire burn out in a fireplace as long as you or someone else will stick around to monitor it until it goes completely out. This may take several hours. To prepare, stop adding fuel to the fire well before you’re ready to call it a night. If you’re using the fireplace for warmth, you’ll want to cover up in some blankets as the flame dies down.

Baking soda is an effective fire reduction method. However, flour and baking powder are very dangerous around flames. Flour is flammable and it can also conduct electricity. The combination can cause serious injury from electrical shock and worsen the situation by adding fuel to the fire. Baking powder is also not an option as it's also highly flammable. 

First, it is crucial to check your local guidelines or building codes. You should typically have one smoke detector for every floor, bedroom, and kitchen. Another rule of thumb is to install one smoke detector for every 500 feet in a home. Reviewing manufacturing recommendations, especially for interconnected devices, is also a good idea to ensure proper connection and monitoring.

The short answer is yes, but the longer answer is more complex. Unless the fireplace is ventless by design, you’ll need some type of exhaust pipe system to safely send fumes and other harmful byproducts out of the house. Even then, ventless fireplaces are not always permitted because they do keep the byproducts inside of your house. Ventless fireplaces are safest when installed in spaces that are themselves well-ventilated, like large rooms with lots of windows.