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Squirrels hate not having access to secure shelter or food sources. Your best line of defense is to make your property less attractive by removing access to these things. There are chemical squirrel repellents, but these have mixed success. According to Pennsylvania State University, you can apply products containing the bittering agent denatonium saccharide to a squirrel's favorite fence, tree, or roof spots. However, you need to reapply repellents regularly, which aren’t scientifically proven effective.

Scorpions cannot climb smooth, non-porous surfaces because their pincers and feet are unable to get a grip. This includes materials like clean glass, polished metal, and slick plastic. While they are excellent climbers on rough or textured surfaces like wood, brick, or stucco, their inability to scale smooth vertical surfaces is why glass jars and other slick containers are effective for trapping them or creating barriers.

Strong scents like peppermint, rosemary, lavender, citronella, and others can repel woodpeckers—as pungent smells can overpower their senses. For that reason, you might consider making a homemade spray with one or a combination of these scents to spritz around areas of your home where woodpeckers frequent.

DIY animal removal is rarely a good idea and is not advised for many reasons. First, these types of animals can carry diseases and, therefore, pose a health risk to you, your family, and your pets if mishandled. Second, depending on your city or municipality, it may be illegal to remove or handle wildlife yourself. 

Sealing your home against these animals yourself is also a bad idea. Trapping an animal under your house will cause odor and insect problems when it passes away.