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Yes, pressure washers can remove rust stains from concrete. However, when coupled with an acid treatment, they can be even more effective. Just be sure to use a minimum of a 15-degree nozzle to prevent damage to the surface, and users must also be careful not to get in the way of the pressure washer’s jet as they can cut through skin and cause injury. 

You should avoid using a pressure washer on any surface or item that could be damaged by the high-pressure spray, as some materials are too delicate to withstand the force.

Key items and surfaces to avoid include:

• Electrical Components: Never pressure wash electrical systems, as water can cause short-circuits and create a safety hazard. This includes utility meters, breaker boxes, electrical outlets, generators, and HVAC or air conditioner units.

• Delicate and Fragile Materials: Fragile items can crack, shatter, or be stripped by the pressure. Avoid pressure washing windows, glass, light fixtures, shingled roofs (especially asphalt), and stucco.

• Painted, Stained, or Sealed Surfaces: Unless your goal is to strip the finish, do not pressure wash painted surfaces, stained wood (like decks), or anything with a protective seal that could be stripped away. Be especially cautious with older surfaces that may contain lead paint.

• Soft Woods and Certain Decking: Delicate surfaces like softwood, composite decking, and antique or wooden patio furniture can be etched or damaged. If you must wash wood, use a lower-powered pressure washer with a wide-angle nozzle to prevent damage.

• Living Things: Never use a pressure washer on people, pets, or plants. The force can cause serious injury and will destroy landscaping.

Yes, baking soda and vinegar can remove rust from concrete. Vinegar is acidic and can remove rust stains from concrete on its own. Adding baking soda may increase abrasiveness, which could help loosen some of the stain even more when scrubbing the stain. However, a stiff-bristled brush can do the same. 

It is generally not recommended to use dish soap in a pressure washer. Dishwashing liquid is formulated for cooler water, and the warmer water used in a pressure washer can create excessive suds, potentially damaging the machine's tubing and other components. Always check the manufacturer’s instructions for recommended detergents. If you find yourself in a pinch, you can try a highly diluted solution, such as one tablespoon of dish soap per 1.5 quarts of water, to avoid clogging the machine.