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No, tiling over painted walls or wallpapered surfaces is generally not recommended. Textured surfaces and paints will affect the adhesive, possibly causing tiles to lift or fall off. Painted walls with a semi-gloss or high-gloss finish are particularly difficult for adding tiles. It’s wise to strip the paint first if you install the tiles to drywall, although it’s still best to opt for a cement backer board.

You can, in theory, tile your fireplace hearth with most tiles. However just because you can, doesn’t mean you should. For example, it’s much better to use unglazed tiles because glazed tiles are more resistant to cracking under extreme heat. Porcelain is more heat-resistant than ceramic, but you can still design the hearth as you like by putting the most heat-resistant tiles directly under the fire and, if it matches your style, add more decorative tiles further from the center of the fire. 

Like glass tiles, you will not need to seal most porcelain tiles, particularly if the porcelain is already glazed. It depends on quality. Porcelain is very water resistant, but it is not 100% waterproof. To avoid staining, some homeowners use a penetrating sealer. It is also a good idea to seal your grout. Unless you use epoxy grout, grout is very porous and can harbor bacteria, mold, and mildew.

When working on your bathroom floor tiling, you should always tile the floor first and then refit the toilet afterward. This has both practical and visual advantages—the tile will have a better seal, and the installation will look cleaner.

On the other hand, when you try to cut the tiles to fit around the toilet, you’re putting yourself at a disadvantage. It’s a lot more work, it’s hard to be precise, and mistakes or miscalculations can lead to future moisture damage to the tiling, grout, and subfloor.