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Yes, brick houses are better insulated, because the bricks slow down the passage of air from the outside to the inside and vice-versa. This helps to stabilize the internal temperature of the home. When combined with proper residential insulation, brick houses are more efficient and better insulated than other types.

It is possible, albeit a lot slower, to break up a rock using water. You would do this by freezing and thawing the water. You could create some initial holes or cracks in the rock, then pour water into the cracks or holes and allow them to freeze (so it's best to do this in winter or in colder climates). Since water expands when it freezes, this puts pressure on the inside of the rock and causes it to crack. You could continue to pour more water in and let it freeze to continue to break up the rock.

To stain brick, you should use a product specifically formulated for brick, concrete, or other masonry surfaces. These stains are designed to penetrate the porous surface of the brick and bond with it. This is different from paint, which sits on the surface and is prone to peeling, flaking, and trapping moisture that can cause damage. Water-based brick stains are often recommended because they are easy to apply, even for DIYers, and they allow the brick to breathe. Avoid using regular paint on brick, as it will not adhere properly and can lead to future maintenance problems.

A fireplace is, by definition, an enclosed space where you burn wood or other fuel for the purpose of generating light and heat. A firepit burns wood and is much less expensive to build, but they aren’t technically a fireplace as it isn’t enclosed. An outdoor oven—commonly outdoor brick pizza ovens—often uses wood as fuel, but its primary purpose is to cook food, and you’d rarely just burn wood inside them for warmth or aesthetic reasons.