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It may sound icky, but yes, urine encourages microbial activity that breaks down organic matter faster. It’s rich in nitrogen, which helps balance carbon-heavy materials like dry leaves or straw. Use sparingly and apply it to a well-balanced pile, not one already high in nitrogen. 

In most cases, it’s better to remove rocks before adding mulch. Layering the two will restrict drainage and plant health, and can create an unpleasant texture underfoot.

For minor unevenness, you don't necessarily need to remove grass before leveling. You can apply a topdressing mixture to fill in low areas and even out the surface. However, for more significant unevenness or deep depressions, it might be necessary to temporarily remove the grass to ensure proper leveling and soil compaction. After filling and leveling, you can replace the grass or consider reseeding the area.

A pre-emergent herbicide is the most effective way to avoid stickers growing in your yard. However, if some manage to make it through, a post-emergent herbicide is the most effective way to kill them. However, environmental concerns exist when using chemicals on a lawn. Try vinegar or baking soda applications to kill sticker plants for a more natural yet still effective method.