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No, definitely not. Pulling weeds by hand is the single most effective way to remove them because you're eliminating the entire plant—roots and all—so it won’t have a chance to grow or spread. Setting time aside a few times per week to pull weeds can keep them at bay. If the number of weeds gets overwhelming, then you can resort to other methods.

Too much clover in your lawn can indicate several issues with your soil. Clover can thrive in soils with abnormally high pH, low-cut grass, and low nitrogen. Amending these issues can push clover out for good.

Hardy perennial clover loves the low nitrogen and compact conditions that often come with poor, infertile soils. But other factors also contribute to a clover explosion, including drought conditions, cool temperatures, under fertilization, and over-irrigation. You’ll need to evaluate all these elements when planning to kill off the clover.

Weeds can grow through rubber mulch, but it depends on if you removed all the weeds in your garden beforehand. Weeds already in the soil can grow even when using rubber mulch. However, that doesn’t mean that your garden will be littered with rubber and weeds, but it does mean that the occasional weed might still pop up. Another way you can increase your weed suppression is by using landscape fabric as a second layer. 

Adding vinegar to your lawn increases the acidity of the area, which can kill quack grass present above the ground. However, putting vinegar in your yard will also kill the grass. Unfortunately, the below-ground quack grass rhizomes remain very much alive in the presence of vinegar and will soon sprout again.