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It may sound icky, but yes, urine encourages microbial activity that breaks down organic matter faster. It’s rich in nitrogen, which helps balance carbon-heavy materials like dry leaves or straw. Use sparingly and apply it to a well-balanced pile, not one already high in nitrogen. 

Depending on the method you choose to remove grass, it may or may not matter whether the grass is wet or dry when you perform the task. A dryer lawn will be easier to negotiate with a sod cutter, especially if you're not planning to reuse the turf. However, using a shovel by hand might be a little easier if the ground is slightly damp but not so much that it sticks to the tool.  

To remove a shrub, start by cutting back the shrub using pruning shears, loppers, or a chainsaw. Next, dig around the base of the shrub with a pointed shovel to expose its root system. Then, use a shovel or a mattock to loosen the roots, making it easier to pull or lift the shrub from the ground. For larger shrubs or stubborn root systems, attaching a chain or strap to the base and using a vehicle to pull it out can be effective. Ensure proper disposal of the shrub and its debris following local waste disposal guidelines.

If your dog always does their business in the yard, daily poop pick-up makes sense. The nitrogen in the poop can start making its way into the grass and surrounding soil quickly, a rain shower can send the waste into waterways, and less poop lying around means less chance of stepping on it accidentally.