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You can paint PVC baseboards. Lightly sand the surface to help the paint adhere, then apply a primer designed for plastics. Use high-quality latex paint for a smooth finish, and ensure the baseboards are clean and dry before starting for best results.

Primer is always recommended for every exterior paint job because it ensures even coverage and long-lasting color. That said, there are high-end brands of paint that market themselves to be easily used without the need for a coat of primer beforehand. It’s up to you which one you choose (and have the budget for), just as long as you read the paint manufacturer’s specific instructions on the product before getting started. 

Lack of durability is the most significant downside of painting tile. However, a painted tile backsplash doesn't see the same kind of action as, say, painted flooring tiles. For backsplashes, the durability of the finish is crucial because they often require cleaning. However, you can minimize the durability problem by using mild cleaners and water on the painted surfaces.

Waterproof paint creates a barrier to hold back moisture, but it doesn’t eliminate the source of the water. If you hire a basement waterproofing contractor, many will tell you that waterproof paint is only a temporary solution. On average, you can expect it to last from six months to two years in a wet basement before deteriorating.