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Weeds can grow through rubber mulch, but it depends on if you removed all the weeds in your garden beforehand. Weeds already in the soil can grow even when using rubber mulch. However, that doesn’t mean that your garden will be littered with rubber and weeds, but it does mean that the occasional weed might still pop up. Another way you can increase your weed suppression is by using landscape fabric as a second layer. 

Yes, suggesting companion planting and mulching to minimize new growth.

The best way to prevent weeds is to use polymeric sand, which hardens and blocks weed growth when activated with water. If you're using regular sand, you'll need to refill and compact it more often. Keeping the surface clean and free of debris can also help prevent weed seeds from settling in the joints.

Like sugar, the common household staple baking soda has uses in the yard. Baking soda boosts your plants to resist pests, fungal growth, and more. So, baking soda is good for your plants in certain instances, but exercise caution, as using too much could kill your plants. It’s great for hunting for pesky weeds, but not great for tending to a sensitive garden.