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Baking soda is an effective fire reduction method. However, flour and baking powder are very dangerous around flames. Flour is flammable and it can also conduct electricity. The combination can cause serious injury from electrical shock and worsen the situation by adding fuel to the fire. Baking powder is also not an option as it's also highly flammable. 

Shiplap can be safe for a gas fireplace, but you should consult with a fireplace installation pro before proceeding. You need to make sure your project meets building and safety codes since shiplap is made from flammable wood. You may need to install another non-combustible material, like stone or brick, around the fireplace for a certain amount of space before you can add shiplap.

Yes, spider webs are flammable, taking them from minor household nuisance to something more dangerous. Silk boasts no built-in resistance to fire, though it takes an abundance of spider webs to actually catch fire and spread. A cobweb here and there poses no major fire safety risk, so it’s not a cause for concern.

No. Removing the cause of concern will only lead to deeper concern. You cannot use any fire-powered appliance like a fireplace or furnace without an escape route for the smoke and fumes. If you remove the flue intending to repair or replace it, you should only use the fireplace, wood stove, or furnace once the flue is in working order. If you cannot replace the flue you have removed, call a chimney repair professional immediately.