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Stains penetrate wood best when it's cool and dry, so you want to avoid moisture. If the wood is wet upon application, or if it rains before the stain dries, the water will soak into the wood and displace the staining solution. This leads to a flaky and blotchy look, which is the opposite of a sumptuous even coat. Once the stain has fully cured, after about 3 days, rain shouldn’t cause you any problems.

You shouldn't paint a metal fence. Painting doesn't necessarily damage a corrugated metal fence, but these types of fences are meant to flex, and paint can easily chip and break off. Latex paints can address this issue, but those tend not to be very weather-resistant. Certain paints can trap moisture in the corrugation, which can rust the metal and lead to corrosion. And finally, if you paint a copper fence, it won't patina, which is one of the main reasons people buy copper.  

Generally, these steps are included in exterior house painting:

• Prepping and protecting the areas not being painted

• Scraping away loose paint

• Cleaning off dirt, grease, and debris

• Caulking gaps and openings

• Priming with a quality paint primer

• Painting the prepared areas, including trim and accents with chosen paint finish

• Adding a second coat

• Cleaning up the site and disposing of tape, plastic, and drop cloths

Your tool of choice ultimately comes down to personal preference. Many DIYers prefer applying stain with a lint-free rag, but others stick with a paint brush or a roller. Wipe the stain and work it into the wood, working with and against the grain. If you’re applying multiple coats, allow the stain to dry for around four hours between coats.