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No, tiling over painted walls or wallpapered surfaces is generally not recommended. Textured surfaces and paints will affect the adhesive, possibly causing tiles to lift or fall off. Painted walls with a semi-gloss or high-gloss finish are particularly difficult for adding tiles. It’s wise to strip the paint first if you install the tiles to drywall, although it’s still best to opt for a cement backer board.

Grout and caulk are commonly used together, especially in bathrooms. Grout goes between the tiles and keeps them sturdy and in place on the walls or floor. Caulk goes in corners or where two different materials meet (like where the bathtub meets the tile) to create a waterproof seal. However, they are not interchangeable—you shouldn't use caulk to adhere tile and shouldn’t use mortar if you need a waterproof seal.

Grouting hearth tiles is one of the most important steps. It seals the tiles so heat doesn’t transfer under the tiles so easily, which can be dangerous. For this reason, heat-resistant grout is a must. Grout also prevents dust, dirt, and any other material from gathering between your tiles. If this happens and those buildups are flammable, a fire could start between the tiles. 

It’s easiest to start from an edge as it gives you a straight line. A problem may arise if your edge doesn’t line up perfectly, in which case it’s best to start from the center. Some think that starting tile from the center adds a focal point in the center of the hearth.