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When buying caulk, look for ones labeled for tub and tile. These have either acrylic latex or silicone compounds. This allows the caulk to stick to smooth surfaces and prevent mildew from forming. 

Bathtubs chip for a number of reasons. The primary cause is simply an accumulation of accidents or direct impact from objects over time. Heavy items will do this, like an iron, but so will lighter objects, like shampoo bottles, especially if you drop them from high enough.

Acrylic tubs can fade or turn yellow over time due to thick layers of accumulated dirt, hard water deposits from minerals, and shampoo or soap dyes. Also, as an acrylic tub ages, it may become dull or change color due to changes in the acrylic itself.

Before you begin caulking a shower, you’ll need to use a utility knife or solvent to remove the old caulk and inspect the area for mold. If needed, take appropriate steps to get rid of the mold, then wipe everything down with dish soap and warm water before letting it dry completely. Finally, surround the caulking area with two strips of blue painter’s tape—one above the joint where you’re caulking and another below it.