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Yes. One of the main benefits of organic mulch is weed prevention. Organic mulch forms a physical barrier that blocks light and stops weeds from germinating. It can reduce your need to weed and improve the physical appearance of your garden.

Weeds can grow through rubber mulch, but it depends on if you removed all the weeds in your garden beforehand. Weeds already in the soil can grow even when using rubber mulch. However, that doesn’t mean that your garden will be littered with rubber and weeds, but it does mean that the occasional weed might still pop up. Another way you can increase your weed suppression is by using landscape fabric as a second layer. 

Vinegar cannot tell the difference between weeds and desired grass types; it kills everything it touches. Only use a vinegar or vinegar-based solution if you are relatively confident that you can navigate around the plants and grasses you want to keep. Also, don’t spray vinegar on a windy day, or it will blow onto other plants.

No, definitely not. Pulling weeds by hand is the single most effective way to remove them because you're eliminating the entire plant—roots and all—so it won’t have a chance to grow or spread. Setting time aside a few times per week to pull weeds can keep them at bay. If the number of weeds gets overwhelming, then you can resort to other methods.