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Vinegar cannot tell the difference between weeds and desired grass types; it kills everything it touches. Only use a vinegar or vinegar-based solution if you are relatively confident that you can navigate around the plants and grasses you want to keep. Also, don’t spray vinegar on a windy day, or it will blow onto other plants.

Pulling weeds can spread weed seeds and disturb the soil, leading to seed germination. Pulling weeds can also trigger growth in weeds that reproduce through their root systems—disturbing the roots without fully removing them may cause more weeds to grow from the roots.

Weeds can grow through rubber mulch, but it depends on if you removed all the weeds in your garden beforehand. Weeds already in the soil can grow even when using rubber mulch. However, that doesn’t mean that your garden will be littered with rubber and weeds, but it does mean that the occasional weed might still pop up. Another way you can increase your weed suppression is by using landscape fabric as a second layer. 

There are several ways to kill poison ivy permanently. The trick is to keep it from coming back. Herbicides and natural remedies are highly effective for killing existing poison ivy plants. However, plant and root parts left behind can easily create new sprouts that turn into full-grown plants. The only way to permanently get rid of poison ivy is to be patient and diligent until all traces of the plant are dead and gone.