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Vinegar and baking soda can be effective for removing old carpet stains, although success may depend on the type of stain. There are two common methods for this process.

One method involves combining the ingredients directly on the stain to create a chemical reaction. First, pour a generous layer of dry baking soda over the stain. In a spray bottle, mix distilled white vinegar with 1 cup of warm water and a few drops of liquid dish soap, then spray this solution thoroughly over the baking soda. The mixture will foam as the acidic vinegar reacts with the basic baking soda, which helps loosen and lift the stain. Let this sit for a few hours until it dries, then wipe or vacuum up the residue and blot the area with a clean, dry towel. You can repeat the process if the stain persists.

An alternative method suggests using the ingredients separately. Start by sprinkling baking soda on the stain and letting it sit for 15 to 30 minutes before vacuuming it up. Next, blot the remaining stain with a solution of equal parts white vinegar and water, and then blot the area dry with a clean cloth.

Eventually, vomit odors will go away on their own. However, it can take weeks for that to happen—unpleasant weeks. Using baking soda or commercially available carpet cleaner according to product directions will speed up the process. 

Most carpet cleaning solutions are safe to use in the home. However, to avoid irritation and health issues you can look for a neutral, mild detergent, especially one that’s marked as nontoxic or eco friendly. When in doubt, always check out the ingredient list. Some cleaning options only use steam heat to clean with little or no detergent, which could be an option if you’re worried. 

The difficulty of cleaning a wool rug will depend on how dirty it is in the first place. For instance, if a wool rug has a build up of stains, this will add to the labor required to clean it. However, cleaning wool rugs should be pretty easy overall as wool naturally repels stains and is a generally durable material.