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Yes. One of the main benefits of organic mulch is weed prevention. Organic mulch forms a physical barrier that blocks light and stops weeds from germinating. It can reduce your need to weed and improve the physical appearance of your garden.

Yellow leaves and stems on your sprouts indicate they’re not getting enough light. Keep them near the appropriate light source and give them as much as they need (they require longer exposure to fluorescence than they do to natural light sources).

Weeds can grow through rubber mulch, but it depends on if you removed all the weeds in your garden beforehand. Weeds already in the soil can grow even when using rubber mulch. However, that doesn’t mean that your garden will be littered with rubber and weeds, but it does mean that the occasional weed might still pop up. Another way you can increase your weed suppression is by using landscape fabric as a second layer. 

Yes, vinegar can be an effective way to kill individual dandelion plants to help in the hand-removal process. However, vinegar can also kill turfgrass, so use a targeted spray.