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No, it’s best not to leave baking soda and vinegar in the drain overnight. While using baking soda and vinegar can be helpful to clear out hair and debris in your bathtub drain, this mixture might start to corrode your drainpipes due to its caustic nature if left in the drain too long or used too often. 

While not every clog has the same symptoms, the most common early sign that your main sewer line is clogged is that multiple drains in your home are draining slowly. You may also notice gurgling and odors from drains. If your plumbing system's drain cleanout is backing up with water, this is also a sign of a clog or blockage.

You could be smelling sewer gas in your kitchen because of a dry P-trap, clogged vent pipe, or leaking plumbing seals. If you smell a rotten egg odor, check your sink’s P-trap and plumbing connections first. A clogged or damaged vent pipe can trap sewer gas and push it back into your kitchen through the plumbing pipes. Loose or deteriorated seals around drainpipes can also allow sewer gas to leak out. If you can’t find the source, call a local plumber for expert help.

In most cases, drain cleaners will not clear a clogged sewer line, and they’re likely to damage your plumbing. Sewer lines are several inches wide, meaning any material that clogs it will need to be large. Drain cleaner can work on small clogs, but it usually won’t clear a larger one in a sewer main. Drain cleaners can also easily damage and corrode your plumbing with prolonged contact, and a clog will keep the cleaner in contact with the pipes for an extended period. Hire a professional sewer cleaner instead for a safe fix.