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Yes, weeds will grow through pea gravel but you can prevent this during the installation process. Install a weed barrier underneath pea gravel and swap it out every three years to keep weeds at bay.

Vinegar cannot tell the difference between weeds and desired grass types; it kills everything it touches. Only use a vinegar or vinegar-based solution if you are relatively confident that you can navigate around the plants and grasses you want to keep. Also, don’t spray vinegar on a windy day, or it will blow onto other plants.

Weeds can grow through rubber mulch, but it depends on if you removed all the weeds in your garden beforehand. Weeds already in the soil can grow even when using rubber mulch. However, that doesn’t mean that your garden will be littered with rubber and weeds, but it does mean that the occasional weed might still pop up. Another way you can increase your weed suppression is by using landscape fabric as a second layer. 

All herbicides come with risks, but you can control and mitigate risks by discussing your options with your weed service company before application. Some companies use milder or sustainable herbicides more times per season to control weeds rather than one to two herbicide sprayings annually. You can also ask your professional about pet-friendly and kid-friendly services. In most cases, though, you can wait a few days after the application for the herbicides to soak into the ground, at that point they shouldn’t pose a risk to you or your family.