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Yes, baking soda and vinegar can remove rust from concrete. Vinegar is acidic and can remove rust stains from concrete on its own. Adding baking soda may increase abrasiveness, which could help loosen some of the stain even more when scrubbing the stain. However, a stiff-bristled brush can do the same. 

The ideal PSI (pounds per square inch) for a pressure washer depends on the surface you are cleaning. For general home use, a pressure washer with a range of 2,000 to 3,000 PSI is recommended and powerful enough for most residential projects.

The specific PSI you should use varies by task:

• High-Pressure Tasks (2,500-3,000 PSI): Tough materials like concrete, stone, masonry, and brick can handle higher pressures. This is suitable for removing stubborn stains from driveways or cleaning graffiti.

• Low-Pressure Tasks (around 600-1,300 PSI): Softer surfaces require a gentler touch to avoid damage. Use a low PSI setting for cleaning wood decks (especially softwoods like pine and cedar), vinyl siding, outdoor furniture, and stucco.

For best results, choose the right nozzle for your surface, such as a 15-degree nozzle for siding or a surface cleaner attachment for driveways. Using an extendable wand can also make the work easier and more ergonomic.

You can certainly utilize a pressure washer to effectively clean your garage floor. If you're dealing with oily residue, consider adding a degreaser to the pressure washer solution. Prior to using the pressure washer, make sure to thoroughly sweep the garage floor to eliminate any loose dirt or debris.

Begin the pressure washing process from the back of your garage, which is closest to your home, and work your way towards the front. This ensures that the water and dirt are directed outside. In case you've applied a cleanser or degreaser, it's a good idea to give the floor another pass with clean water using the pressure washer to ensure a thorough rinse.

It depends on the type of surface, but if you’re preparing to pressure wash a driveway, you’ll start by using a broom or leaf blower to get rid of dirt, leaves, and other debris. Then, move any nearby items (like outdoor furniture and potted plants) and cover in-ground plants with a tarp or plastic sheet. After that, you can apply degreaser spray or another pretreatment solution to any stains and scrub them with a stiff brush before pressure washing.