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Weeds can grow through rubber mulch, but it depends on if you removed all the weeds in your garden beforehand. Weeds already in the soil can grow even when using rubber mulch. However, that doesn’t mean that your garden will be littered with rubber and weeds, but it does mean that the occasional weed might still pop up. Another way you can increase your weed suppression is by using landscape fabric as a second layer. 

Pulling weeds once per month is typically often enough to keep most weeds at bay. But in general, it's best to pull weeds as soon as you spot them to prevent deep root growth and slow their spread. To make it easier, plan your weed pulling after rain or after the sprinklers run so the soil will be nice and wet and the weeds will be easier to pull. If you notice moss accompanying weeds, make a plan to remove the moss immediately to prevent damage.

Yes, organic herbicides and natural prevention methods reduce chemical use.

Technically, dandelions aren’t bad for your lawn, and they don’t directly kill grass. In fact, they appear in areas that are nutrient-deprived, and their long taproots can loosen the soil and bring nutrients closer to the surface. 

However, dandelions do spread quickly, and they can take over your lawn, eventually crowding out grass. This is why a healthy lawn is the best defense against dandelions.