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That pungent rotten egg smell coming from your drain is likely the buildup of biofilm—hair, skin, and soap scum that turns into a black sticky mess. In this case, pouring down near-boiling water, baking soda, and white vinegar will remove the smell. Keep in mind that a rotten egg smell is occasionally a sign of larger sewage line clogs and other related issues.

There are many things that could cause your basement floor drain to back up. One significant cause of a drainage backup is flushing non-flushable items, such as wipes, paper towels, and facial tissue. Other causes of a backed-up basement floor drain include tree roots impeding the drain pipe or an accumulation of hair, oil, and grease. 

There are a few reasons your snake won’t go down the floor drain. One common reason is a large obstruction in the drain that is causing a blockage. You can remove any debris you see in the drain before trying to snake it. In addition, the snake might not be long enough to reach the clog, or it might be the wrong diameter. 

Boiling water helps unclog a drain, but usually only with a harder abrasive such as baking soda or vinegar. On its own, it isn’t the most effective tool. In addition, you shouldn’t use boiling water if you have PVC pipes, as it can soften or melt them. Use a plunger or enlist the help of a pro if you have plastic pipes.